Why Successive Electronic Affinities Have Negative Values

A student recently asked me why successive electron affinities can have negative values. Here’s a quick explanation: First, let’s clarify what we mean by successive electron affinity. It refers to the energy change when adding a second, third, or subsequent electron to an already negatively charged ion, after one electron has been added to the … Read more

Bragg Slater Radii

In the previous section, we saw that since the exact size of an atom is difficult to determine, chemists use different types of atomic radii—such as covalent, van der Waals, ionic, and metallic radii—each defined according to the type of bonding involved. There is also the Bragg–Slater radius, which provides another way to estimate atomic … Read more

Atomic Radii vs Metallic Radii

The term atomic radius generally refers to the distance from the center of an atom’s nucleus to the outermost shell of its electrons. However, determining the exact size of an atom is challenging because atoms do not have sharply defined boundaries. Moreover, it’s impossible to isolate a single atom and measure its radius directly. Therefore, … Read more