Mixtures and Compounds

In the previous section, we’ve learnt that a compound is a pure substance that is made up of two or more elements chemically combined. We also learnt in previous sections that that matter exists as pure substances and mixtures.

So, what is the difference between a mixture and a compound?

Well, the difference between a mixture and a compound can become clearer when we consider the scenario of combining iron fillings and sulfur: imagine grinding them together and attempting to separate them using a magnet. Then, heating the mixture strongly and again attempting to separate the new substance formed using a magnet.

When you try to septate the mixture with a magnet before heating them, the iron fillings are attracted to the magnet, making it easy to separate iron from Sulphur.

On heating, a black solid is formed, which cannot be separated into its constituents using a magnet.  

The results indicate that before the iron-Sulphur mixture was heated, its components (iron and Sulphur) retained their properties. That’s why we could take advantage of iron’s magnetic property to separate the mixture.  

When the mixture is heated, iron and Sulphur combine to form a new substance with unique properties that are different from those or iron and Sulphur. The new substance is Iron (II) sulphide.

We know that Iron and Sulphur are elements. Before heating, we had simply a mixture of two elements, with each having its own unique properties.

On heating, Iron and Sulphur particles combine chemically to form a new substance with totally different properties. The two elements are now bound together by a chemical bond, which is so strong and would require an input of significant amount of energy to break and separate the two elements.

The Iron (II) sulphide is a compound, which has been formed by chemically combining two elements. Iron and Sulphur are now chemically bonded and cannot be separated by a magnet.     

Distinct Formation Characteristics

The formation of the new substance (compound) has certain features that are very distinct from the formation of a mixture. These include:

  • Heat change is involved. Unlike obtaining a mixture, which involved simply mixing iron fillings with Sulphur powder, we had to heat the mixture to obtain Iron (II) sulphide compound.
  • In making a mixture, all we had to do is add variable amounts of each component. In forming the compound, however, the constituent elements combined based on a fixed ratio by mass. For instance, in the formation of Iron (II) sulphide, iron and Sulphur are known to combine in the ration of 3.5:2. This means that if there is an excess of one constituent, it will remain after the reaction.  So we can deduce that compounds have fixed compositions.

Mixtures Vs Compounds Summary

Here is a summary to help you understand the differences between mixtures and compounds:

MixturesCompounds
No new substances are formed during formationA new substance (s) is formed during formation
Can be separated into constituent substances by physical means  Cannot be separated into constituent substances by physical means  
No chemical changes occurs during formationSubstances combine chemically
Components can be in any proportion by massComponent elements have fixed compositions by mass
No heat change occurs during formationHeat is produced or absorbed during formation
Individual components show their unique propertiesProperties of new substances are different from those of constituent elements
Contains at least two substancesAre single substances
Are considered to be impure substancesAre considered to be pure substances
No new chemical bond formation takes placeNew chemical bonds are formed during formation
Cannot be represented by chemical formulaCan be represented by chemical formula (Nacl, KNO3, CaCl2, etc)
Examples include Salt in water, Sulphur in iron fillings, oil and water, pasta and sauce, smoke and fog, etcExamples include water, sodium chloride (NaCl), baking soda, sodium bicarbonate (NaHCO3), Hydrochloric acid, etc

Further Reading

How to Tell Which Elements Are Present in a Compound from Its Name: The Ate, Ite, & Ide Suffixes

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